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JOURNALS // Izvestiya of Saratov University. Physics // Archive

Izv. Sarat. Univ. Physics, 2008 Volume 8, Issue 1, Pages 42–47 (Mi isuph415)

This article is cited in 1 paper

Physics

The investigation of the 4-butil-4'-cyanobiphenyl IR spectra transformations at the temperature changes

L. M. Babkova, I. I. Gnatyukb, G. A. Puchkovskayab, S. V. Truckhacheva

a Saratov State University
b Institute of Physics, National Academy of Sciences of Ukraine

Abstract: The IR spectra of the 4-butil-4'-cyanobiphenyl in the liquid and solid crystal states in the region 400–400 cm$^{-1}$ were measured at the 28–70$^{\circ}$Ñ temperature interval. The transformations of the spectra at the temperature changes are explained on the basis of the IR spectra calculation results performed with using of the LEV-100 software. A supposition about the conformational changes in the molecule made. The bands sensitive to the changes in its conformational structure were found and the interpretation of the IR spectra was given.

Keywords: temperature changes, spectra, conformation of the molecule.

UDC: 539.196,3

Received: 20.01.2008

DOI: 10.18500/1817-3020-2008-8-1-42-47



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