Abstract:
The basic equations for the study of phase transition "dielectric - metal" in ionic crystals of infinite
size at absolute zero temperature are obtained. "Dielectric - metal" phase transition pressures for the
number of alkali-halide crystals are calculated. Relative changes in the volume of the crystal modifications at the phase transition "dielectric - metal" in ionic crystals are calculated. The calculation of the cohesive characteristics of the dielectric and metallic phases of ionic crystals is performed. Phase diagrams
for all the investigated crystals are plotted.