Abstract:
It is found that CF 2HCl molecules dissociate under irradiation by high-intensity pulses of femtosecond radiation (λ=1.8 μm) in the vicinity of resonance with the frequency of overtone vibrational transitions in the C-H bond. It is shown that the dissociation products substantially differ from the products of dissociation of CF2HCl molecules from the ground and excited electronic states under the action of IR and UV nanosecond pulses.