Detection of magnetic resonance signals with anomalous dispersion and two types of isolated manganese centers in the chalcopyrite crystal (Zn,Mn)GeP$_2$
Abstract:
Anomalously intense dispersion was observed in the magnetic resonance signals of manganese clusters in the chalcopyrite crystal ZnGeP$_2$:Mn with a high concentration of manganese. The EPR signals detected corresponded to two types of isolated manganese ions. One of these apparently possesses acceptor properties, which makes manganese a self-contained impurity for the formation of a ferromagnetic state in accordance with recent theoretical predictions.