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JOURNALS // Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki // Archive

Pis'ma v Zh. Èksper. Teoret. Fiz., 2002 Volume 75, Issue 1, Pages 25–27 (Mi jetpl3016)

This article is cited in 28 papers

CONDENSED MATTER

Equation of state and structural phase transition in FeBO$\mathbf{_3}$ at high pressure

A. G. Gavriliuka, I. A. Trojana, R. Boehlerb, M. I. Eremetsb, A. Zerrc, I. S. Lyubutind, V. A. Sarkisyand

a Institute for High Pressure Physics, Russian Academy of Sciences
b Max-Planck Institut fuer Chemie, Mainz
c Technische Universität Darmstadt, FB Material- und Geowissenschaften
d Institute of Cristallography Russian Academy of Sciences, Moscow

Abstract: Evolution of X-ray diffraction patterns in FeBO$_3$ under high pressures up to 63 GPa has been investigated at room temperature in a diamond anvil cell. A structural phase transition at pressure of $53\pm2 \,$GPa was found for the first time. The transition is of the first- order type with the hysteresisless drop of the reduced unit cell volume of about 8.6%. Apparently, the transition is isostructural. At pressures below the transition, the equation of state for FeBO$_3$ was fitted. In approximation of the third order Birch-Murnagan equation of state, the bulk modulus $K$ and its first pressure derivative $K'$ were found to be $255 \pm25 \,$GPa and $5.0 \pm 1.2$, respectively.

PACS: 61.50.Ks, 64.60.-i, 64.70.Kb

Received: 23.11.2001

Language: English


 English version:
Journal of Experimental and Theoretical Physics Letters, 2002, 75:1, 23–25

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