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JOURNALS // Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki // Archive

Pis'ma v Zh. Èksper. Teoret. Fiz., 2001 Volume 74, Issue 7, Pages 440–442 (Mi jetpl4232)

This article is cited in 3 papers

CONDENSED MATTER

Synthesis of a new magnetic Y$_2$Mn$_{2/3}$Re$_{4/3}$O$_7$ with pyrochlore-like structure

G. V. Bazuev, T. I. Chupakhina, V. N. Krasil'nikov

Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg

Abstract: A complex oxide of the Y$_2$Mn$_{2/3}$Re$_{4/3}$O$_7$ composition with pyrochlore-like structure and parameters of hexagonal unit cell $\alpha=14.91(1)$ Å, $c=17.53(1)$ Å was synthesized. The magnetic susceptibility and magnetization measurements showed that below 190 K this oxide possesses spontaneous magnetic moment. In the paramegnetic region, the magnetic susceptibility obeys the Curie-Weiss law $\chi=C/(T-\theta)$, with $C=2.07\,$cm$^3\cdot{}$K/mol$^{-1}$ and $\theta=-160$ K, and the effective magnetic moment corresponding to the cationic combination Mn$^{2+}$-Re$^{5+}$. The data obtained allow one to assume that the compound has a noncollinear antiferromagnetic structure

PACS: 75.20.Hr, 75.50.-y

Received: 03.09.2001


 English version:
Journal of Experimental and Theoretical Physics Letters, 2001, 74:7, 401–403

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