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CONDENSED MATTER
Relaxation kinetics of the microhardness of KDP crystals after their exposure to a magnetic field
E. V. Darinskayaa,
M. V. Koldaevaa,
V. I. Alshitsa,
I. M. Pritulab,
A. E. Voloshina a Shubnikov Institute of Crystallography, Federal Research Center Crystallography and Photonics, Russian Academy of Sciences, Moscow, Russia
b Institute of Single Crystals, National Academy of Sciences of Ukraine, Kharkiv, Ukraine
Abstract:
It has been shown that potassium dihydrogen phosphate crystals change their microhardness reversibly after their exposure to a magnetic field of
$B=0.8$ or
$1.2$ T for
$t_{\mathrm{m}}=7{-}90\,$ min. It has been found that the magnetic effect can be conveniently characterized by the quantity
$B^2t_{\mathrm{m}}$, because the variation of the parameters conserving
$B^2t_{\mathrm{m}}=\mathrm{const}$ does not change the result. At
$B^2t_{\mathrm{m}}<10\,$T
$^2$ min, the effect is almost absent. Above this threshold, the amplitude of changes in the microhardness increases and approaches a constant value of
$\sim10\%$ at
$B^2t_{\mathrm{m}}\approx19\,$T
$^2$ min. The responses of samples of the same crystal from the faces of the prismatic and pyramidal growth sectors to exposure are different. In the former case, they soften; in the latter case, the hardening stage follows the softening stage. However, in both cases, the microhardness returns to the initial value. At
$B^2t_{\mathrm{m}}$ values from
$19$ to
$37$ T
$^2$ min, the amplitudes and durations of the effect do not change, but in the narrow range of
$37$–
$43$ T
$^2$ min, the lifetime of the modified state increases sharply with transition to a new level: “sharp” peaks with a half-width of
$\sim2$ days are transformed to trapezoids with the width of the horizontal side of
$\sim1$–
$2$weeks. A physical scheme of the observed effects has been proposed.
Received: 04.07.2018
DOI:
10.1134/S0370274X18160038