Acceleration of the decay of excitons in an organometallic perovskite film on the crystalline silicon surface

It has been found that the optical properties and characteristics of exciton photoluminescence in thin organometallic perovskite layers, which are promising for application in high-efficiency solar cells, change when these layers are deposited on a crystalline silicon (c-Si) substrate. The observed shift of the photoluminescence band toward higher photon energies and a decrease in the lifetime of photoluminescence compared to layers deposited on a glass substrate with conducting metal oxide coating have been explained by the effect of an electric field that is formed in an organometallic perovskite/c-Si heterostructure and leads to the field ionization and the decay of excitons in the organometallic perovskite layer.