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JOURNALS // Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki // Archive

Pis'ma v Zh. Èksper. Teoret. Fiz., 2024 Volume 119, Issue 11, Pages 825–830 (Mi jetpl7244)

CONDENSED MATTER

Isentropic compression of solid CO$_2$ at megabar pressures

V. D. Selemira, V. V. Brazhkinb, K. D. Litasovb, P. B. Repina, A. S. Korshunova, A. I. Bykova, G. V. Boriskova, N. I. Egorova, Yu. B. Kudasova, I. V. Makarova, D. A. Maslova, V. N. Pavlova, V. V. Platonova, I. S. Strelkova, O. M. Surdina, R. V. Kozabaranova, A. V. Bochkareva, A. A. Agapova, N. A. Belyaevaa

a Russian Federal Nuclear Center All-Russian Scientific Research Institute of Experimental Physics, Sarov, Nizhny Novgorod region, 607188 Russia
b Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow, 108840 Russia

Abstract: Experiments on the dynamic isentropic compression of solid CO$_2$ samples by the megabar pressure induced by the superstrong magnetic field of an explosive magnetic generator have been performed with the X-ray diffraction detection of the state of the compressed samples. The generator operation is based on the fast compression of the initial magnetic flux in the cavity of the generator by a conducting cylindrical liner accelerated by the products of the explosion of a cylindrical explosive charge. Two points at pressures of 349 and 459 GPa on the compressibility diagram of CO$_2$ have been determined in the experiments, where the degree of compression $\rho/\rho_0$ of CO$_2$ has reached currently highest values of 3.90 and 4.02, respectively. Comparison has shown that theoretically calculated equations of states for crystal phases of CO$_2$ almost completely reproduce the experimental results, which confirms a high accuracy of theoretical predictions and the identity of the experimental and theoretical equations of states of CO$_2$ modifications stable at high pressures.

Received: 18.04.2024
Revised: 18.04.2024
Accepted: 21.04.2024

DOI: 10.31857/S1234567824110089


 English version:
Journal of Experimental and Theoretical Physics Letters, 2024, 119:11, 860–864


© Steklov Math. Inst. of RAS, 2024