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Zhurnal Tekhnicheskoi Fiziki, 2021 Volume 91, Issue 6, Pages 964–969 (Mi jtf4992)

Physical science of materials

A crossover in methanol fuel cell with modified graphene membrane

A. F. Vyatkina, E. V. Gerasimovab, O. V. Kononenkoa

a Institute of Microelectronics Technology and High-Purity Materials RAS
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region

Abstract: The possibility of modifying the nafion direct alcohol fuel cell proton-exchange membrane by monolayer graphene by hot pressing has been demonstrated. It is shown that this modification can reduce the permeability of the membrane on methanol while maintaining a high proton conductivity membrane, but with the long operation of the membrane without additional protection of the barrier layer formed in this way, it is detached. With a Nafion/graphene/Nafion membrane, the formed graphene layer is sufficiently protected to reduce the methanol crossover and increase the power of the single methanol fuel cell by 2 times.

Keywords: graphene, crossover, membrane, permeability, fuel cell.

Received: 08.10.2020
Revised: 15.12.2020
Accepted: 16.12.2020

DOI: 10.21883/JTF.2021.06.50866.284-20



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