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Zhurnal Tekhnicheskoi Fiziki, 2021 Volume 91, Issue 5, Pages 778–783 (Mi jtf5013)

Solids

The influence of the composition on the atomic structure of Bi$_{1-x}$Y$_{x}$FeO$_{3}$ ceramics

Z. A. Samoilenkoa, N. N. Ivakhnenkoab, E. I. Pushenkoa, V. Ya. Sychevaa, N. A. Ledeneva, A. V. Pashchenkoa

a O O Galkin Donetsk Institute for Physics and Engineering, National Academy of Sciences of Ukraine
b Tugan-Baranovsky National University of Economics and Trade, Donetsk, Ukraine

Abstract: The atomic structure in Bi$_{1-x}$Y$_{x}$FeO$_{3}$ samples is analyzed as a function of changes in the concentration composition of yttrium at $x$ = 0, 0.1, 0.15, 0.2. The samples were prepared by fast liquid sintering using a conventional solid state reaction. As a result of X-ray diffraction studies of Bi$_{1-x}$Y$_{x}$FeO$_{3}$ samples with increasing $x$, a concentration phase transition from the rhombohedral phase to the orthorhombic phase was revealed at $x$ = 0.2 and the inflection point $x$ = 0.15. It was shown that with an increase in the yttrium content, the relative dielectric constants and dielectric loss tangents of the samples gradually decreased.

Keywords: multiferroics, bismuth ferrite, concentration phase transition, dielectric constant, dielectric loss tangent.

Received: 18.07.2020
Revised: 10.11.2020
Accepted: 22.11.2020

DOI: 10.21883/JTF.2021.05.50689.228-20


 English version:
Technical Physics, 2021, 66:6, 793–797

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© Steklov Math. Inst. of RAS, 2024