Abstract:
The effects that the presence of silicon atoms in the zone of electric arc used for evaporation of graphite electrodes has on the efficiency of formation of higher fullerenes C$_{76}$, C$_{78}$, Ñ$_{80}$, Ñ$_{82}$, C$_{84}$, Ñ$_{86}$, etc., are studied. Optimization of the evaporation conditions and the use of composite graphite electrodes containing silicon carbide, the additive, in the range of 0 to 6.3 wt% enables us to produce soot with the fullerene content at up to 15.5 wt% in a soot extract and, at the time, achieve a high net fullerene yield of 10.5% of the soot weight.
Keywords:fullerenes, higher fullerenes, silicon carbide, electric arc synthesis, HPLC.