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JOURNALS // Zhurnal Tekhnicheskoi Fiziki // Archive

Zhurnal Tekhnicheskoi Fiziki, 2020 Volume 90, Issue 1, Pages 110–114 (Mi jtf5415)

This article is cited in 2 papers

Physical science of materials

Role of silicon carbide in arc discharge synthesis of higher fullerenes

I. E. Kareeva, A. E. Dutlovb, V. P. Bubnova

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
b Lomonosov Moscow State University

Abstract: The effects that the presence of silicon atoms in the zone of electric arc used for evaporation of graphite electrodes has on the efficiency of formation of higher fullerenes C$_{76}$, C$_{78}$, Ñ$_{80}$, Ñ$_{82}$, C$_{84}$, Ñ$_{86}$, etc., are studied. Optimization of the evaporation conditions and the use of composite graphite electrodes containing silicon carbide, the additive, in the range of 0 to 6.3 wt% enables us to produce soot with the fullerene content at up to 15.5 wt% in a soot extract and, at the time, achieve a high net fullerene yield of 10.5% of the soot weight.

Keywords: fullerenes, higher fullerenes, silicon carbide, electric arc synthesis, HPLC.

Received: 25.03.2019
Revised: 17.04.2019
Accepted: 21.07.2019

DOI: 10.21883/JTF.2020.01.48670.108-19


 English version:
Technical Physics, 2020, 65:1, 102–106

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