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Zhurnal Tekhnicheskoi Fiziki, 2019 Volume 89, Issue 6, Pages 803–811 (Mi jtf5581)

This article is cited in 1 paper

Theoretical and Mathematical Physics

Application of quantum scattering theory in calculation of the simplest chemical reactions (dissociative attachment, dissociation, and recombination)

S. A. Pozdneev

P. N. Lebedev Physical Institute of the Russian Academy of Sciences, Moscow

Abstract: Several parameters (cross section, reaction rate, etc.) of various processes in laser, atomic, and chemical physics are calculated using quantum scattering theory for a system of a few particles. Results of the study of electronic and atomic collisions with diatomic molecules and collisions of diatomic molecules in excited rovibrational states are discussed. Several approximations needed for calculations of real physical systems consisting of several bodies are analyzed. Such approximations can be used for simulation of direct reactions and reactions that yield intermediate transient complexes. Calculated cross sections of electronic and atomic collisions with diatomic molecules and collisions of diatomic molecules are compared with experimental data and results of alternative calculations.

Received: 08.10.2018
Revised: 02.11.2018
Accepted: 04.12.2018

DOI: 10.21883/JTF.2019.06.47625.363-18


 English version:
Technical Physics, 2019, 64:6, 749–756

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