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Zhurnal Tekhnicheskoi Fiziki, 2018 Volume 88, Issue 3, Pages 409–417 (Mi jtf5971)

Solid-State Electronics

Specifics of the electrical properties of composite solid oxide membranes based on SrTi$_{0.5}$Fe$_{0.5}$O$_{3-\delta}$

V. V. Sal'nikova, E. Yu. Pikalovaab, A. A. Kolchuginab, I. V. Nikolaenkobc

a Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia
b Ural Federal University Yekaterinburg, Russia
c Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg

Abstract: The electrical properties of dual-phase fluorite-pervoskite oxide systems based on strontium titanate- ferrite (SrTi$_{0.5}$Fe$_{0.5}$O$_{3-\delta}$) are studied. We find that the oxygen ionic and ambipolar conductivities of strontium titanate-ferrite can be considerably improved by introducing the fluorite phase Ce$_{0.8}$(Sm$_{0.8}$Sr$_{0.2}$)$_{0.2}$O$_{2-\delta}$. This is advantageous considering the prospects of applying these types of composite materials in different electrochemical devices, e.g., as membrane materials in electrochemical converters for the production of hydrogen and syngas and anode materials in solid oxide fuel cells.

Received: 14.03.2017

DOI: 10.21883/JTF.2018.03.45599.2246


 English version:
Technical Physics, 2018, 63:3, 398–406

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