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Zhurnal Tekhnicheskoi Fiziki, 2024 Volume 94, Issue 2, Pages 207–215 (Mi jtf6704)

Solids

Feature of infiltration under the action of capillary forces of the silicon melt to a great depth of porous carbon material

V. A. Tyumentseva, A. G. Fazlitdinovaa, A. B. Liberzonb

a Chelyabinsk State University, 454001 Chelyabinsk, Russia
b SilKam, 454780 Ozersk, Chelyabinsk Region, Russia

Abstract: The results of X-ray diffraction and electron microscopic studies of composite materials obtained in the process of directional impregnation from bottom to top of carbon bases differing in porosity at a temperature of $\ge$ 1500$^\circ$C with a KR-00 grade silicon melt are considered. Results of in situ observation of the interaction of silicon melt with a porous carbon base. It is shown that an increase in the apparent density of the porous carbon matrix over 1.452 g/cm$^3$ limits the height of silicon melt infiltration; In the transition region, only SiC phases and graphite are present; the silicon melt that enters this region completely enters into solid-phase interaction with carbon. The surface of the largest pores turned out to be covered with a layer of silicon carbide.

Keywords: carbon-silicon carbide composite, reactive infiltration, X-ray diffraction analysis, phase composition.

Received: 02.08.2023
Revised: 28.11.2023
Accepted: 25.12.2023

DOI: 10.61011/JTF.2024.02.57074.195-23



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© Steklov Math. Inst. of RAS, 2025