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Zhurnal Tekhnicheskoi Fiziki, 2025 Volume 95, Issue 1, Pages 56–78 (Mi jtf7084)

Solids

Theory of the structure of icosahedral quasicrystals: types of packings

A. E. Madisona, P. A. Madisonab

a National Research University "Higher School of Economics", St. Petersburg Branch, St. Petersburg, Russia
b Saint Petersburg Electrotechnical University "LETI", St. Petersburg, Russia

Abstract: A unified theory of the structure of icosahedral quasicrystals is proposed. All possible variants of self-similar icosahedral packings are analyzed. These include 3 types of quasi-lattices $(P, I, F)$, which are analogues of primitive, body-centered and face-centered cubic lattices; each of them can be either centrosymmetric or non-centrosymmetric. Substitution rules for $I$ and $F$-type tetrahedral tilings are fully formalized. An example of constructing a non-centrosymmetric $I$-type packing is presented. A method is shown for generating a zonohedral packing $(P)$ from a tetrahedral packing $(I)$ by joining the neighboring tetrahedra in it. For each packing type, 3 locally isomorphic patches are possible, differing in the choice of node in its center $\mathrm{(A, B, C)}$. When the tetrahedral packings are built up, three locally isomorphic patches cyclically transform into each other after each iteration. As a consequence, the structures of the three types of characteristic clusters are not independent. An icosahedral packing of any type can be constructed based on a unified algorithm when initialized with a single tetrahedron.

Keywords: icosahedral quasicrystals, substitution rules, packings.

Received: 08.09.2024
Revised: 20.11.2024
Accepted: 29.11.2024

DOI: 10.61011/JTF.2025.01.59489.269-24



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© Steklov Math. Inst. of RAS, 2025