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Zhurnal Tekhnicheskoi Fiziki, 2025 Volume 95, Issue 2, Pages 373–384 (Mi jtf7209)

Special issue on the materials of the International Conference "Nanocarbon and Diamond" (NiA'2024)
Physical science of materials

Stable sols of carboxylated diamond nanoparticles in dimethyl sulfoxide

D. È. Martyanov, A. T. Dideikin, A. D. Trofimuk, A. Ya. Vul'

Ioffe Institute, St. Petersburg, Russia

Abstract: Stable sols of detonation synthesis diamond nanoparticles with negative electrokinetic potential in dimethyl sulfoxide, one of the most common non-aqueous solvents widely used in organic synthesis and medicine, were obtained for the first time. Sol stability is achieved by steric stabilization of the surface of diamond nanoparticles due to a cationic surfactant, cetyltrimethylammonium bromide, which binds to the carboxyl groups of diamond nanoparticles. The obtained stable sols can be used for subsequent chemical modification of the surface of diamond nanoparticles.

Keywords: diamond nanoparticles, detonation synthesis, dimethyl sulfoxide, sols, stability of colloidal systems, surfactants.

Received: 29.10.2024
Revised: 29.10.2024
Accepted: 29.10.2024

DOI: 10.61011/JTF.2025.02.59734.369-24



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© Steklov Math. Inst. of RAS, 2025