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Zhurnal Tekhnicheskoi Fiziki, 2022 Volume 92, Issue 6, Pages 815–821 (Mi jtf7363)

Physical science of materials

Crystals of the phenazine coordination polymer with the third order symmetry axis: formation, properties

M. E. Kompana, V. G. Malyshkina, M. E. Boikoa, M. D. Sharkova, I. Yu. Sapurinab, M. A. Shishovbc

a Ioffe Institute, St. Petersburg, Russia
b Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia
c Peter the Great St. Petersburg Polytechnic University, 195251 St. Petersburg, Russia

Abstract: Unusual quasi-two-dimensional crystals of a regular triangular shape, self-formed in the process of obtaining a coordination polymer based on phenazine and silver, are described and studied. X-ray diffraction studies were carried out, the interplanar distance was determined, and the spectra of Raman scattering were obtained. A mechanism is proposed that can cause the appearance of triangular crystals from nuclei of hexagonal symmetry.

Keywords: X-ray diffractometry, Raman scattering, phenazines – organic crystals.

Received: 17.12.2021
Revised: 15.02.2022
Accepted: 14.03.2022

DOI: 10.21883/JTF.2022.06.52510.319-21



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