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Zhurnal Tekhnicheskoi Fiziki, 2022 Volume 92, Issue 12, Pages 1781–1786 (Mi jtf7486)

Theoretical and Mathematical Physics

Identification of fast hydrogen permeability parameters of gas separation membranes

Yu. V. Zaikaa, N. I. Sidorovb, O. V. Fomkinac

a Institute of Applied Mathematical Research of Karelian Research Centre Russian Academy of Sciences, 185910 Petrozavodsk, Russia
b Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, 620016 Ekaterinburg, Russia
c High School of Economics, 198008 St. Petersburg, Russia

Abstract: The problem of parametric identification of some nonlinear models of fast hydrogen permeability of alloys for membrane technologies for the release of high-purity hydrogen (on the example of alloy B1) is solved. Not only diffusion in the bulk of the material is taken into account, but also physical and chemical processes on the surface: adsorption, desorption and rapid dissolution. The mathematical software and the results of numerical simulation for a three-stage breakthrough experiment with vacuum pumping at the membrane outlet from the structural material under study are presented. The influence of the accumulation of atomic hydrogen on the surface has been studied.

Keywords: hydrogen permeability, membrane technology of gas separation, parametric model identification.

Received: 15.08.2022
Revised: 30.09.2022
Accepted: 02.10.2022

DOI: 10.21883/JTF.2022.12.53744.205-22



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