V. K. Brel, A. V. Vologzhanina, M. T. Metlin, I. V. Taidakov, “Synthesis, crystal structure and luminescent properties of a novel coordination polymer built on Eu<sup>iii</sup> and 1,2,4,5-tetrakis(diphenylphosphinyl)benzene”, Mendeleev Commun., 2024, Volume 34, Issue 3,Pages <nobr>329

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Synthesis, crystal structure and luminescent properties of a novel coordination polymer built on Euⁱⁱⁱ and 1,2,4,5-tetrakis(diphenylphosphinyl)benzene

V. K. Brel^a, A. V. Vologzhanina^a, M. T. Metlin^bc, I. V. Taidakov^db

^a A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
^b P. N. Lebedev Physical Institute of the Russian Academy of Sciences, Moscow
^c Bauman Moscow State Technical University
^d N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences

Abstract: The reaction of 1,2,4,5-tetrakis(diphenylphosphinyl)benzene with Eu(ONO₂)₃∙6H₂O led to the formation of a new coordination polymer exhibiting a bright red glow when excited in a wide ultraviolet range (Qin = 19.9%).

Keywords: 1,2,4,5-tetrakis(diphenylphosphinyl), benzeneEuⁱⁱⁱ complexes, MOF, X-ray diffraction analysis, luminescence.

Received: 18.12.2023

Language: English

DOI: 10.1016/j.mencom.2024.04.006