I. A. Lutsenko, M. A. Kiskin, D. E. Baravikov, Yu. V. Nelyubina, P. V. Primakov, I. L. Eremenko, “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach”, Mendeleev Commun., 2021, Volume 31, Issue 5,Pages 628

This article is cited in 3 papers

Communications

Chemical design of heterometallic carboxylate structures with Fe³⁺ and Ag⁺ ions as a rational synthetic approach

I. A. Lutsenko^a, M. A. Kiskin^a, D. E. Baravikov^a, Yu. V. Nelyubina^b, P. V. Primakov^b, I. L. Eremenko^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Solid phase thermolysis of pivalate complex [Fe₃O(Piv)₆(HPiv)₃]Piv generates the [Fe₃O(Piv)₆]⁺ complex cation due to a deficiency of ligands in the coordination sphere of the metal ions. Crystallization of [Fe₃O(Piv)₆]⁺ from THF–EtOH leads to the heteroleptic complex [Fe₃O(Piv)₆(THF)(EtOH)(OH)] · 0.5 THF · 0.5 H₂O in 69% yield, while the reaction of [Fe₃O(Piv)₆]⁺ with AgNO₃ in toluene results in the complex [Fe₄Ag₄O₂(Piv)₁₂] · 2 PhMe with a rare combination of Fe^III and Ag^I atoms. Crystal structures of the two new complexes have been established.

Keywords: iron complex, solid phase thermolysis, heteroleptic complex, silver, crystal structure.

Language: English

DOI: 10.1016/j.mencom.2021.09.012