Mendeleev Commun., 2021 Volume 31, Issue 5, Pages 677–679
(Mi mendc1020)
This article is cited in
8 papers
Communications Arylhydrazones of α-keto esters via methanolysis of dichlorodiazabutadienes: synthesis and structural study N. G. Shikhaliyev a ,
A. M. Maharramov a ,
G. T. Suleymanova a ,
A. A. Babazade a ,
V. G. Nenajdenko b ,
V. N. Khrustalev cd ,
A. S. Novikov e ,
A. G. Tskhovrebov df a Department of Chemistry, Baku State University, Baku, Azerbaijan
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation d Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation e Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation f N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation Abstract:
Novel approach to methyl 2-aryl-2-(arylhydrazono) acetates
via methanolysis of dichlorodiazabutadienes was developed. Hydrogen bonding in methyl
Z -2-phenyl-2-(phenyl-hydrazono) acetate was explored by DFT calculations and topological analysis of the electron density distribution within the framework of Bader’s theory (QTAIM method).
Keywords:
keto esters, hydrazones, hydrogen bonding, DFT, QTAIM, calculations, methanolysis.
Language: English
DOI:
10.1016/j.mencom.2021.09.028
© , 2025
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