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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2024 Volume 34, Issue 2, Pages 270–271 (Mi mendc104)

Communications

β-Cyclodextrin-stabilized Cu nanoparticles catalyzed C–O coupling to access 2-aryloxypyridines

Y. Zhoua, Ya.-J. Fanb, L. Wangab

a School of Petrochemical Engineering, Changzhou University, Changzhou, China
b School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China

Abstract: β-Cyclodextrin-stabilized Cu nanoparticles were prepared from CuSO4⋅5H2O using sodium hydroxymethanesulfinate (rongalite) as the reducing agent and β-cyclodextrin as the stabilizing agent. This nanocatalyst showed good catalytic activities in the C–O coupling of phenols with 2-bromopyridine providing 2-aryloxypyridines in moderate to good yields. The catalyst can be recovered and reused five times with slight decrease in its activity.

Keywords: C–O coupling, copper nanoparticles, 2-aryloxypyridines, rongalite, β-cyclodextrin.

Language: English

DOI: 10.1016/j.mencom.2024.02.035



© Steklov Math. Inst. of RAS, 2025