D. B. Vinogradov, P. V. Bulatov, E. Yu. Petrov, V. A. Tartakovsky, “New access to azido-substituted alkylnitramines”, Mendeleev Commun., 2021, Volume 31, Issue 6,Pages <nobr>795

This article is cited in 10 papers

Communications

New access to azido-substituted alkylnitramines

D. B. Vinogradov, P. V. Bulatov, E. Yu. Petrov, V. A. Tartakovsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A new versatile access to azido-substituted N-alkylnitramines is based on ring opening in N-nitrooxazolidines and N-nitroperhydro-1,3-oxazines with thionyl chloride followed by treatment with sodium azide. Representative N,N-bis(azidoalkyl)- and N-azidoalkyl-N-methoxymethyl- containing nitramines were synthesized and characterized.

Keywords: N-nitrooxazolidine, N-nitroperhydro-1,3-oxazine, nitramine, azides, thionyl chloride, chlorination, α,μ-dichloro-2-nitro- 2-azaalkanes, azidation, phase transfer catalyst.

Language: English

DOI: 10.1016/j.mencom.2021.11.008

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