Mendeleev Commun., 2021 Volume 31, Issue 6, Pages 853–855
(Mi mendc1065)
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20 papers
Communications Significant impact of lanthanide contraction on the structure of the phenanthroline complexes P. S. Lemport a ,
M. V. Evsiunina a ,
Yu. V. Nelyubina b ,
K. L. Isakovskaya bc ,
V. N. Khrustalev de ,
V. S. Petrov a ,
A. S. Pozdeev a ,
P. I. Matveev a ,
Yu. A. Ustynyuk a ,
V. G. Nenajdenko a a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation c D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation e Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation Abstract:
The structure of La, Nd, Eu and Lu complexes with
N ,
N ,
N' ,
N' -tetrabutyl-1,10-phenanthroline-2,9-dicarbox- amide ligand was examined using X-ray diffraction analysis. Due to the effect of lanthanide contraction, lutetium forms unique type of complex having the coordination number 9 in contrast to other 10-coordinated lanthanides.
Keywords:
phenanthrolinediamide, polydentate ligand, lanthanide, complex, lutetium complexes, X-ray, coordination number.
Language: English
DOI:
10.1016/j.mencom.2021.11.028
© , 2025
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