I. D. Strelnik, I. R. Dayanova, T. M. Poryvaev, T. P. Gerasimova, I. A. Litvinov, S. A. Katsyuba, E. I. Musina, A. A. Karasik, O. G. Sinyashin, “Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template”, Mendeleev Commun., 2020, Volume 30, Issue 1,Pages 40

This article is cited in 7 papers

Communications

Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P₄N₄ ligand on the gold(i) template

I. D. Strelnik, I. R. Dayanova, T. M. Poryvaev, T. P. Gerasimova, I. A. Litvinov, S. A. Katsyuba, E. I. Musina, A. A. Karasik, O. G. Sinyashin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reaction of gold(i) chloride with two molecules of 1,5-diaza-3,7-diphosphacyclooctane derivative causes their reorganization into 16-membered macrocyclic tetraphosphine ligand. The structure of the trinuclear gold(i) complex obtained was confirmed by X-ray analysis. The dynamic equilibrium between dinuclear gold(i) complexes with eight-membered cyclic ligands and the trinuclear gold(i) complex with 16-membered ones has been revealed.

Keywords: tertiary phosphines, gold(i) complexes, aminomethylphosphines, macrocyclic ligands.

Language: English

DOI: 10.1016/j.mencom.2020.01.013

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