V. A. Kokorekin, E. I. Melnikova, R. R. Yaubasarova, V. A. Petrosyan, “Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity”, Mendeleev Commun., 2020, Volume 30, Issue 1,Pages <nobr>70

This article is cited in 8 papers

Communications

Electrooxidative C–H thiocyanation of hetarenes: voltammetric assessment of thiocyanogen reactivity

V. A. Kokorekin^ab, E. I. Melnikova^a, R. R. Yaubasarova^a, V. A. Petrosyan^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b I.M. Sechenov First Moscow State Medical University, Moscow, Russian Federation

Abstract: The height of thiocyanogen reduction peak on cyclic voltammograms of thiocyanate ion can serve as the criterion for thiocyanogen reactivity towards hetarenes present in the electrolyte. This allows one to predict the efficiency of anodic thiocyanation of various hetarenes.

Keywords: electrosynthesis, aryl thiocyanates, electrooxidative C–H functionalization, hetarenes, nucleophiles, cyclic voltammetry.

Language: English

DOI: 10.1016/j.mencom.2020.01.023