M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand”, Mendeleev Commun., 2020, Volume 30, Issue 1,Pages <nobr>94

This article is cited in 14 papers

Communications

One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand

M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: Treatment of a bulky dbhmp-bian ligand (dbhmp-bian==1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH₄ or mixture of 3/4 equiv. LiAlH₄ and 1/3 eqiuv. AlCl₃ in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]^-[Li(THF)₄]⁺ and (dbhmp-bian)AlH(THF), respectively. Both complexes were characterized by spectroscopic (IR, NMR) and X-ray diffraction methods.

Keywords: aluminum hydrides, imines, acenaphthenes, sterically hindered ligands, diimine ligands, redox-active ligands.

Language: English

DOI: 10.1016/j.mencom.2020.01.031

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