RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2020 Volume 30, Issue 1, Pages 100–102 (Mi mendc1114)

This article is cited in 3 papers

Communications

Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands

H. Wangab, N. Wua, J. Zhenga, Ch. Zhengab, D. Wanga

a Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University, Huangshi, P.R. China
b Department of Chemistry, The School of Art and Science of Hubei Normal University, Huangshi, P.R. China

Abstract: Three polypyridine ligands such as tri(2-pyridyl)methane, (2,2-bipyridin-6-yl)di(2-pyridyl)methane and 2,6-bis[di(2-pyridyl)methyl] pyridine as well as their new iron(II) mononuclear complexes have been obtained in a one-pot synthesis. Detailed structural analyses and magnetic susceptibility measurements confirm the expected six-coordinate octahedral geometry and the metric parameters are consistent with lowspin iron(II) in the complexes.

Keywords: polypyridine, one-pot synthesis, metal complexes, low-spin.

Language: English

DOI: 10.1016/j.mencom.2020.01.033



© Steklov Math. Inst. of RAS, 2025