V. G. Krasovskiy, G. I. Kapustin, L. M. Glukhov, O. B. Gorbatsevich, E. A. Chernikova, A. A. Koroteev, L. M. Kustov, “Dicationic disiloxane ionic liquids”, Mendeleev Commun., 2020, Volume 30, Issue 1,Pages <nobr>114–116</nobr>

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Mendeleev Commun., 2020 Volume 30, Issue 1, Pages 114–116 (Mi mendc1119)

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Communications

Dicationic disiloxane ionic liquids

V. G. Krasovskiy^a, G. I. Kapustin^a, L. M. Glukhov^a, O. B. Gorbatsevich^b, E. A. Chernikova^a, A. A. Koroteev^c, L. M. Kustov^ad

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
^c Moscow Aviation Institute (National Research University), Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Bis(trifluoromethylsulfonyl)imide ionic liquids containing disiloxane linkers between imidazole cations were synthesized. Their hydrolytic and thermal stabilities were explored, and melting points, viscosities, and volatilities in vacuo were measured. The effect of nature of the substituents at imidazole cations on the set of properties of the synthesized ionic liquids was revealed.

Keywords: dicationic liquids, disiloxane linker, hydrolytic and thermal stability, viscosity, volatility..

Language: English

DOI: 10.1016/j.mencom.2020.01.038

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