I. A. Abdulaeva, D. A. Polivanovskaia, K. P. Birin, Yu. G. Gorbunova, A. Yu. Tsivadze, “A panchromatic pyrazine-fused porphyrin dimer”, Mendeleev Commun., 2020, Volume 30, Issue 2,Pages <nobr>162

This article is cited in 11 papers

Communications

A panchromatic pyrazine-fused porphyrin dimer

I. A. Abdulaeva^a, D. A. Polivanovskaia^a, K. P. Birin^a, Yu. G. Gorbunova^ab, A. Yu. Tsivadze^ab

^a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New pyrazine-fused porphyrin dimer was unexpectedly produced by mild oxidation of [2,3-diamino-5,10,15,20-tetrakis(4-butoxyphenyl)porphyrinato]nickel(ii) in 40% yield. The obtained porphyrin dimer demonstrates bathochromic shift of absorption bands compared to the reported analogues, along with panchromatic absorption in the 250–650nm range, which is promising for optical, photovoltaic and medical applications.

Keywords: pyrazine-fused dimers, porphyrins, diamines, oxidation, nickel complexes, panchromatic absorption.

Language: English

DOI: 10.1016/j.mencom.2020.03.010

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