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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2020 Volume 30, Issue 2, Pages 238–240 (Mi mendc1161)

This article is cited in 4 papers

Communications

An expedient one-pot synthesis of benzophenone Schiff bases from benzene

I. S. Akhrem, L. V. Afanas'eva, D. V. Avetisyan, O. I. Artyushin, N. D. Kagramanov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A simple and efficient one-pot synthesis of benzophenone Schiff bases from benzene, CCl4 and aromatic amines was developed based on the the reaction of benzene with CCl4·AlCl3 complex. This method affords Ph2CCl2 as well as the products of its subsequent reaction with aromatic amines, benzophenone Schiff bases, selectively and in good yields.

Keywords: one-pot synthesis, benzene, Schiff bases, tetrachloromethane, benzophenone, aluminum trichloride.

Language: English

DOI: 10.1016/j.mencom.2020.03.037



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