N. I. Vorozhtsov, D. D. Korablina, L. A. Sviridova, V. A. Tafeenko, A. A. Moiseeva, N. V. Zyk, E. K. Beloglazkina, “Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(<sc>ii</sc>) chloride”, Mendeleev Commun., 2020, Volume 30, Issue 2,Pages <nobr>244

This article is cited in 2 papers

Communications

Unusual complexation of 1-phenylthiocarbamoyl-3-(pyridin-2-yl)pyrazoline with copper(ii) chloride

N. I. Vorozhtsov, D. D. Korablina, L. A. Sviridova, V. A. Tafeenko, A. A. Moiseeva, N. V. Zyk, E. K. Beloglazkina

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Complexation of 5-(4-dimethylaminophenyl)-1-phenylthiocarbamoyl-3-(pyridin-2-yl)-4,5-dihydro-1H-pyrazole with CuCl₂ followed by recrystallization from alcohols as external nucleophiles affords the products of pyrazoline ring opening by thiosemicarbazone moiety. The structure of the obtained complex was confirmed by X-ray diffraction data.

Keywords: copper(ii) complexes, thiosemicarbazone complexes, pyrazolines, ring opening, alcohols, X-ray.

Language: English

DOI: 10.1016/j.mencom.2020.03.039

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