I. V. Morozov, E. Kemnitz, S. I. Troyanov, “Hydrogen bonds in mixed bifluoride–nitrate salts of ammonium and potassium”, Mendeleev Commun., 2020, Volume 30, Issue 3,Pages <nobr>291

This article is cited in 1 paper

Communications

Hydrogen bonds in mixed bifluoride–nitrate salts of ammonium and potassium

I. V. Morozov^a, E. Kemnitz^b, S. I. Troyanov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Chemistry, Humboldt University, Berlin, Germany

Abstract: The salts (NH₄)₂(HF₂)(NO₃) and K₃(HF₂)(NO₃)₂ were isolated by crystallization from aqueous bifluoride and nitrate solutions. The crystal structures of the ammonium and potassium salts contain short hydrogen bonds in bifluoride anions (HF₂)⁻ with F···F distances of 2.277(5) and 2.237(1)Å, respectively, and the latter is the shortest among all ever reported hydrogen bonds in metal bifluorides.

Keywords: bifluoride, nitrate, potassium, ammonium, hydrogen bond, crystal structure.

Language: English

DOI: 10.1016/j.mencom.2020.05.009