Mendeleev Commun., 2020 Volume 30, Issue 3, Pages 293–295
(Mi mendc1174)
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13 papers
Communications Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate D. S. Yambulatov a ,
P. A. Petrov bc ,
Yu. V. Nelyubina ad ,
A. A. Starikova e ,
A. A. Pavlov d ,
D. Y. Aleshin d ,
S. A. Nikolaevskii a ,
M. A. Kiskin a ,
M. N. Sokolov bc ,
I. L. Eremenko ad a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation c Novosibirsk State University, Novosibirsk, Russian Federation d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation e Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation Abstract:
An adduct of Zn
II pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.
Keywords:
N-heterocyclic carbenes, carboxylate complexes, zinc(II), DFT calculations, X-ray crystallography.
Language: English
DOI:
10.1016/j.mencom.2020.05.010
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