M. I. Rogovoy, M. P. Davydova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes”, Mendeleev Commun., 2020, Volume 30, Issue 3,Pages 305

This article is cited in 6 papers

Communications

Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its Ag^I, Au^I and Pt^II complexes

M. I. Rogovoy^a, M. P. Davydova^a, I. Yu. Bagryanskaya^b, A. V. Artem'ev^a

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine has been developed based on reaction of Ph₃P with metallic lithium followed by treatment of the Ph₂PLi formed with 2-chloropyrazine. The Ag^I, Au^I and Pt^II chloride complexes derived from this phosphine have been synthesized and structurally characterized.

Keywords: diphenyl(pyrazin-2-yl)phosphine, lithiation, pyrazine, triphenylphosphine, silver(I) complexes, gold(I) complexes, platinum(II) complexes.

Language: English

DOI: 10.1016/j.mencom.2020.05.014

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