N. G. Yakhontov, O. B. Gorbatsevich, A. A. Kalinina, N. V. Demchenko, V. V. Kazakova, A. M. Muzafarov, “Hydrolytic polycondensation of trimethoxymethylsilane under ultrasonic irradiation”, Mendeleev Commun., 2020, Volume 30, Issue 3,Pages <nobr>336

This article is cited in 7 papers

Communications

Hydrolytic polycondensation of trimethoxymethylsilane under ultrasonic irradiation

N. G. Yakhontov^a, O. B. Gorbatsevich^b, A. A. Kalinina^b, N. V. Demchenko^b, V. V. Kazakova^b, A. M. Muzafarov^bc

^a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
^b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The hydrolytic polycondensation of trimethoxymethylsilane in the absence of catalyst and solvent under ultrasonic irradiation was performed, the effect of reagent ratio, power, temperature and irradiation duration on the process outcome was estimated. Thus obtained polyorganosilsesquioxanes were characterized by ¹H NMR and IR spectroscopy as well as gel permeation chromatography.

Keywords: hydrolytic polycondensation, alkoxysilanes, trimethoxymethylsilane, polyorganosilsesquioxanes, ultrasonic irradiation.

Language: English

DOI: 10.1016/j.mencom.2020.05.025

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