A. I. Gaysin, T. A. Vakhonina, E. O. Yakovleva, M. Yu. Balakina, O. G. Sinyashin, “Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure”, Mendeleev Commun., 2024, Volume 34, Issue 3,Pages 332

Communications

Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure

A. I. Gaysin, T. A. Vakhonina, E. O. Yakovleva, M. Yu. Balakina, O. G. Sinyashin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: A precursor for the production of azo chromophores, viz. 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate, was prepared and characterized. Its copolymerization with methyl methacrylate was carried out and the copolymerization constants were determined: for 2-hydroxy-3-(N-methyl-N-phenylamino) propyl methacrylate, r₁ = 0.50; for methyl methacrylate, r₂ = 0.93. The average block lengths of monomers of the same type depending on the composition of the copolymer were estimated.

Keywords: radical polymerization, methacrylic copolymers, nonlinear optical polymers, comonomer reactivity ratios, probability of bonds formation, copolymer microstructure, 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate.

Language: English

DOI: 10.1016/j.mencom.2024.04.007

	*Supplementary materials:*
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