I. S. Borisov, D. Yu. Mladentsev, B. A. Guzeev, G. P. Goryunov, D. V. Uborsky, A. Vittoria, R. Cipullo, V. Busico, N. Friederichs, A. Z. Voskoboynikov, “Synthesis and olefin polymerization performance of new <i>ans</i>a-zirconocene with OSiO-bridged bis(2-indenyl) ligand”, Mendeleev Commun., 2020, Volume 30, Issue 4,Pages <nobr>449

This article is cited in 3 papers

Communications

Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand

I. S. Borisov^a, D. Yu. Mladentsev^a, B. A. Guzeev^a, G. P. Goryunov^a, D. V. Uborsky^a, A. Vittoria^b, R. Cipullo^b, V. Busico^b, N. Friederichs^c, A. Z. Voskoboynikov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Napoli, Italy
^c SABIC, Technology and Innovation Department, Geleen, The Netherlands

Abstract: New ansa-zirconocene with bis(inden-2-yloxy)dimethylsilane ligand was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The zirconocene was found to be highly active catalyst of ethylene polymerization and ethylene/hex-1-ene copolymerization upon methylaluminoxane activation.

Keywords: ansa-metallocenes, LLDPE, olefin polymerization, single-site catalysts, X-ray crystallography.

Language: English

DOI: 10.1016/j.mencom.2020.07.014

	*Supplementary materials:*
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