A. G. Dedov, A. A. Karavaev, A. S. Loktev, A. S. Mitinenko, I. E. Mukhin, E. A. Isaeva, E. V. Rogaleva, I. I. Moiseev, “Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts”, Mendeleev Commun., 2020, Volume 30, Issue 4,Pages <nobr>459

This article is cited in 2 papers

Communications

Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts

A. G. Dedov^ab, A. A. Karavaev^b, A. S. Loktev^ab, A. S. Mitinenko^a, I. E. Mukhin^a, E. A. Isaeva^a, E. V. Rogaleva^a, I. I. Moiseev^ab

^a National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Ethyl acetate conversion over MFI zeolite-based catalysts synthesized by the hydrothermal-microwave method was investigated for the first time. MFI zeolites in the proton form and promoted with zinc and chromium catalyzed ethyl acetate conversion to liquid hydrocarbons with an almost 100% content of aromatic hydrocarbons. Moreover, the content of the benzene–toluene–xylene (BTX) fraction in aromatic hydrocarbons reached 92–93 wt%.

Keywords: ethyl acetate, renewable raw materials, hydrothermal-microwave synthesis, MFI zeolites, aromatic hydrocarbons.

Language: English

DOI: 10.1016/j.mencom.2020.07.017

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