V. V. Baranov, Ya. A. Barsegyan, Yu. A. Strelenko, V. A. Karnoukhova, A. N. Kravchenko, “New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines”, Mendeleev Commun., 2020, Volume 30, Issue 4,Pages <nobr>479

This article is cited in 6 papers

Communications

New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines

V. V. Baranov^a, Ya. A. Barsegyan^a, Yu. A. Strelenko^a, V. A. Karnoukhova^b, A. N. Kravchenko^ac

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: New aspects of multicomponent condensation reactions of ethylene/propylenediamine, formaldehyde and unsubstituted and 1-methyl substituted semithio- and dithioglycolurils have been examined. Ethylene-linked 2,3a,4a,6,9,10a,11aheptaaza-6,9-methanobenzo[cd]cyclonona[gh]pentalene and 2,6:10,14-dimethano-2,6,7a,8a,10,14,15a,16a-octaazadicyclodeca[cd,gh]pentalene as well as their simpler analogues were synthesized, and their structures were proved by 1D and 2D NMR spectroscopy, HRMS and X-ray analysis.

Keywords: thioglycolurils, multicomponent reactions, diamines, polyheterocycles, formaldehyde, aminals.

Language: English

DOI: 10.1016/j.mencom.2020.07.024

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