A. A. Melnikov, I. P. Pozdnyakov, S. V. Chekalin, E. M. Glebov, “Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex”, Mendeleev Commun., 2020, Volume 30, Issue 4,Pages 509

This article is cited in 4 papers

Communications

Direct measurement of ultrafast intersystem crossing time for the PtIVBr₆²⁻ complex

A. A. Melnikov^ab, I. P. Pozdnyakov^cd, S. V. Chekalin^a, E. M. Glebov^cd

^a Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow, Russian Federation
^b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
^c V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^d Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: The time of ultrafast intersystem crossing for the PtIVBr₆^2– complex in aqueous solution was measured by a fluorescence up-conversion technique. The corresponding time constant (140 ± 40 fs) is in agreement with that estimated from previous ultrafast transient absorption measurements and with the reported results of theoretical calculations.

Keywords: fluorescence up-conversion, ultrafast dynamics, ultrafast intersystem crossing, PtBr₆²⁻ complex.

Language: English

DOI: 10.1016/j.mencom.2020.07.036