I. V. Krylova, E. A. Saverina, S. S. Rynin, A. V. Lalov, M. E. Minyaev, E. N. Nikolaevskaya, M. A. Syroeshkin, M. P. Egorov, “Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>563

This article is cited in 8 papers

Communications

Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system

I. V. Krylova^a, E. A. Saverina^ab, S. S. Rynin^a, A. V. Lalov^a, M. E. Minyaev^a, E. N. Nikolaevskaya^a, M. A. Syroeshkin^a, M. P. Egorov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Institut des Sciences Chimiques de Rennes, University of Rennes, Rennes, France

Abstract: New Schiff base germanate derivative containing the chain Ar–C=N→Ge←N=C–Ar was synthesized and characterized by physical methods including X-ray diffraction. The stability of the corresponding radical anion obtained electrochemically was confirmed by cyclic voltammetry, the results were compared with UV-VIS data and quantum chemical calculations.

Keywords: germanium complexes, salens, redox chemistry, Schiff bases, cyclic voltammetry, radical ions, DFT calculations.

Language: English

DOI: 10.1016/j.mencom.2020.09.003

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