V. Romanovs, D. M. Vakhrusheva, I. V. Krylova, B. N. Mankaev, A. Ya. Kozmenkova, M. A. Syroeshkin, M. P. Egorov, V. Jouikov, “1,1′-Diphenyl-bis-germatrane with persistent radical cation”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>567

This article is cited in 5 papers

Communications

1,1′-Diphenyl-bis-germatrane with persistent radical cation

V. Romanovs^a, D. M. Vakhrusheva^bc, I. V. Krylova^b, B. N. Mankaev^d, A. Ya. Kozmenkova^b, M. A. Syroeshkin^b, M. P. Egorov^b, V. Jouikov^e

^a Latvian Institute of Organic Synthesis, Riga, Latvian Republic
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^e Chimie et Photonique Moleculaires, Universite de Rennes I, Rennes, France

Abstract: Bis-phenyl derivative of a novel family of bis-metallatranes, 1,1′-diphenyl-bis-germatrane, was synthesized and characterized. One-electron oxidation of this compound is electrochemically and chemically reversible providing a persistent radical cation.

Keywords: organogermanium compounds, metallatranes, redox properties, radical cations, cyclic voltammetry, actuator systems.

Language: English

DOI: 10.1016/j.mencom.2020.09.004

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