L. Fu, Q. Yang, D. Li, J. Y. Lu, “New 3D metal–organic framework isomer containing trinuclear oxo-centered mixed valence iron”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>589

This article is cited in 3 papers

Communications

New 3D metal–organic framework isomer containing trinuclear oxo-centered mixed valence iron

L. Fu^ab, Q. Yang^b, D. Li^c, J. Y. Lu^a

^a Department of Chemistry, University of Houston-Clear Lake, Houston, TX, USA
^b College of Chemistry and Materials Science, Northwest University, Xi’an, Shaanxi, P.R. China
^c College of Materials and Chemical Engineering, China Three Gorges University, Yichang, P.R. China.

Abstract: Reaction of FeCl₂·4H₂O, 5-bromonicotinic acid and 4,4′-bipyridine under hydrothermal conditions produced a new isomer of [(Feⁱⁱⁱ)2Feⁱⁱ(μ₃-O)(5-bromonicotinato)₆]n, which represented 3D metal–organic covalent framework with trinuclear oxo-centered mixed valence iron clusters. Crystal structure of the isomer has been characterized by single crystal X-ray diffraction data and found distinct from the one for the known isomer with 2D structure.

Keywords: coordination polymer, crystal structure, 5-bromonicotinic acid, μ-oxo-centered, trinuclear mixed valence iron.

Language: English

DOI: 10.1016/j.mencom.2020.09.012

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