I. N. Meshcheryakova, K. V. Arsenyeva, G. K. Fukin, V. K. Cherkasov, A. V. Piskunov, “Stable N-heterocyclic carbene derivatives of copper(<sc>i</sc>) and silver(<sc>i</sc>) containing radical anion redox active ligands”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>592

This article is cited in 7 papers

Communications

Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands

I. N. Meshcheryakova, K. V. Arsenyeva, G. K. Fukin, V. K. Cherkasov, A. V. Piskunov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: N-Heterocyclic carbene is a versatile ligand for the preparation of copper(i) and silver(i) derivatives bearing the radical anion forms of redox active o-benzoquinone and o-iminobenzoquinone. The paramagnetic three-coordinated copper(i) and silver(i) o-benzosemiquinone and o-iminobenzosemiquinone complexes were prepared and characterized by EPR spectroscopy and X-ray diffraction analysis.

Keywords: N-heterocyclic carbene, copper(i), silver(i), redox active ligand, o-benzosemiquinone, o-iminobenzosemiquinone, X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2020.09.013

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