E. A. Kuchuk, B. N. Mankaev, V. A. Serova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, G. S. Zaitseva, S. S. Karlov, “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>596

This article is cited in 8 papers

Communications

New dialkylenetriamine zinc complexes as highly efficient ROP catalysts

E. A. Kuchuk^a, B. N. Mankaev^a, V. A. Serova^a, K. V. Zaitsev^a, A. V. Churakov^b, Yu. F. Oprunenko^a, G. S. Zaitseva^a, S. S. Karlov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reaction of Zn[N(SiMe₃)₂]₂ with N-alkyl-N-[ω- (pentafluorophenylamino)alkyl]-N-[2-(pentafluorophenylamino) ethyl]amines afforded new bicyclic zinc complexes. The complexes initiate ring-opening polymerization of ɛ-caprolactone and trimethylene carbonate to give the corresponding polymers with high molecular weight and satisfactory degree of polymerization.

Keywords: ring-opening polymerization, diamides, amines, zinc complex, biodegradable polymers, ɛ-caprolactone, trimethylene carbonate, 1,4,n-triazaalkanes, organofluorine compounds.

Language: English

DOI: 10.1016/j.mencom.2020.09.014

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