M. Yu. Zaremski, E. E. Aliev, E. S. Garina, N. S. Melik-Nubarov, “TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>627

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Communications

TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer

M. Yu. Zaremski, E. E. Aliev, E. S. Garina, N. S. Melik-Nubarov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A new synthesis of poly(methyl methacrylate) vinylterminated macromonomer is performed using the disproportionation between propagating methyl methacrylate radical and nitroxide TEMPO. The ability of the macromonomer to polymerize and copolymerize with styrene and poly(ethylene glycol) methacrylate was confirmed by GPC and isothermal calorimetry.

Keywords: macromonomers, nitroxides, radical polymerization, poly(methyl methacrylate), disproportionation, terminal vinyl group, brush-like copolymers.

Language: English

DOI: 10.1016/j.mencom.2020.09.025

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