E. D. Mordvinova, O. A. Snytnikova, V. A. Salomatova, V. V. Yanshole, V. P. Grivin, I. P. Pozdnyakov, “Direct UVC photodegradation of imipramine in aqueous solutions: a mechanistic study”, Mendeleev Commun., 2020, Volume 30, Issue 5,Pages <nobr>654

This article is cited in 2 papers

Communications

Direct UVC photodegradation of imipramine in aqueous solutions: a mechanistic study

E. D. Mordvinova^ab, O. A. Snytnikova^bc, V. A. Salomatova^ab, V. V. Yanshole^bc, V. P. Grivin^ab, I. P. Pozdnyakov^ab

^a V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Novosibirsk State University, Novosibirsk, Russian Federation
^c International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Mechanism of direct UVC photolysis of dibenzazepine-type drug imipramine (IMI) was revealed by the combination of laser flash photolysis for the detection of short lived intermediates and steady-state photolysis coupled with LC-MS for identification of final products. Both quantum yield of IMI photoionization and molar absorption coefficient of IMI radical cation were determined for the first time.

Keywords: pharmaceuticals, dibenzazepines, antidepressants, UVC photolysis, laser flash photolysis, photodegradation, radicals, photoionization, water treatment.

Language: English

DOI: 10.1016/j.mencom.2020.09.034

	*Supplementary materials:*
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