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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2020 Volume 30, Issue 6, Pages 719–721 (Mi mendc1303)

This article is cited in 4 papers

Communications

Photoinduced solid-state isomerization and structural characterization of a nitro–nitrosyl ruthenium complex with 3-cyanopyridine

A. A. Mikhailov, D. P. Pishchur, N. V. Kuratieva, G. A. Kostin

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The title complex, which is crystallized in a noncentrosymmetric space group due to specific intermolecular interactions, exhibits reversible light-induced nitrosyl linkage isomerism; thus, it is of interest for studying combined Ru–NO ↔ Ru–ON isomerization with non-linear optical properties.

Keywords: ruthenium, nitrosyl, nitric oxide, linkage isomers, photoisomerization, molecular switch.

Language: English

DOI: 10.1016/j.mencom.2020.11.010



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